|
|
tigloyl-CoA + 13-hydroxylupanine <=> 13-tigloyloxylupanine + CoA
|
2.3.1.93
13-hydroxylupanine O-tigloyltransferase
|
–
|
MK
|
|
BRENDA:
BR44096
KEGG:
R04205
MetaCyc:
RXN-8694
|
|
|
|
(2S,3S)-3-hydroxy-2-methylbutanoyl-CoA <=> tigloyl-CoA + H2O
|
4.2.1.17
enoyl-CoA hydratase
|
–
|
MK
|
|
BRENDA:
BS444413
KEGG:
R04204
MetaCyc:
TIGLYLCOA-HYDROXY-RXN
SABIO-RK:
3920
|
|
|
|
2-methylbutanoyl-CoA + flavin <=> tigloyl-CoA + reduced_flavodoxin + H+
|
1.3.8.5
2-methyl-branched-chain-enoyl-CoA reductase
1.3.99.12
2-methylacyl-CoA dehydrogenase
|
–
–
|
|
|
BRENDA:
BR1200
KEGG:
R03169
|
|
|
|
2-methylbutanoyl-CoA + acceptor <=> tigloyl-CoA + reduced_acceptor
|
1.3.8.1
short-chain acyl-CoA dehydrogenase
1.3.99.12
2-methylacyl-CoA dehydrogenase
|
–
–
|
|
|
BRENDA:
BR36850
KEGG:
R03173
|
|
|
|
(S)-2-methylbutanoyl-CoA + acceptor <=> tigloyl-CoA + reduced_acceptor
|
1.3.8.1
short-chain acyl-CoA dehydrogenase
1.3.8.7
medium-chain acyl-CoA dehydrogenase
1.3.99.12
2-methylacyl-CoA dehydrogenase
|
–
–
–
|
K
|
|
BRENDA:
BS258775
KEGG:
R03172
|
|
|
|
tigloyl-CoA + H2O <=> CoA + (E)-2-methyl-2-butenoate
|
3.1.2.20
acyl-CoA hydrolase
|
–
|
|
|
BRENDA:
BS402024
SABIO-RK:
12799
|
|
|
|
(S)-2-methylbutanoyl-CoA + oxidized_electron_transfer_flavoprotein + H+ <=> tigloyl-CoA + reduced_flavodoxin
|
1.3.8.5
2-methyl-branched-chain-enoyl-CoA reductase
|
–
|
M
|
|
MetaCyc:
2-METHYLACYL-COA-DEHYDROGENASE-RXN
|
|
|
|
3-hydroxyisovaleryl-CoA <=> tigloyl-CoA + H2O
|
4.2.1.17
enoyl-CoA hydratase
|
–
|
|
|
MetaCyc:
RXN-14266
|
|
|
|
(S)-2-methylbutanoyl-CoA + flavin <=> tigloyl-CoA + reduced_flavodoxin
|
1.3.8.4
isovaleryl-CoA dehydrogenase
|
–
|
|
|
BRENDA:
BS425198
|
|
|
|
tigloyl-CoA + Tropine <=> CoA + O-tigloyltropine
|
2.3.1.185
tropine acyltransferase
|
–
|
|
|
BRENDA:
BS393679
|
|
|
|
tigloyl-CoA + N-ethylnortropan-3-ol <=> CoA + 8-ethyl-8-azabicyclo[3.2.1]oct-3-yl_(2E)-2-methylbut-2-enoate
|
2.3.1.185
tropine acyltransferase
2.3.1.186
pseudotropine acyltransferase
|
–
–
|
|
|
BRENDA:
BS393672
|
|
|
|
tigloyl-CoA + N-(2-fluoroethyl)nortropan-3-ol <=> CoA + 3-O-tigloyl-N-(2-fluoroethyl)nortropan-3-ol
|
2.3.1.186
pseudotropine acyltransferase
|
–
|
|
|
BRENDA:
BS393670
|
|
|
|
tigloyl-CoA + 13-alpha-hydroxymultiflorine <=> CoA + 13-tigloyloxymultiflorine
|
2.3.1.93
13-hydroxylupanine O-tigloyltransferase
|
–
|
|
|
BRENDA:
BS321495
|
|
|
|
tigloyl-CoA + norpseudopelletierin-3-ol <=> CoA + 3-O-tigloyl-norpseudopelletierin-3-ol
|
2.3.1.186
pseudotropine acyltransferase
|
–
|
|
|
BRENDA:
BS393676
|
|
|
|
tigloyl-CoA + pseudotropine <=> CoA + O-(3-methylcrotonyl)pseudotropine
|
2.3.1.186
pseudotropine acyltransferase
|
–
|
|
|
BRENDA:
BS393678
|
|
|
|
tigloyl-CoA + N-ethylnorpseudopelletierin-3-ol <=> CoA + 3-O-tigloyl-N-ethylnorpseudopelletierin-3-ol
|
2.3.1.186
pseudotropine acyltransferase
|
–
|
|
|
BRENDA:
BS393671
|
|
|
|
tigloyl-CoA + N-iso-propylnorpseudopelletierin-3-ol <=> CoA + 3-O-tigloyl-N-iso-propylnorpseudopelletierin-3-ol
|
2.3.1.186
pseudotropine acyltransferase
|
–
|
|
|
BRENDA:
BS393674
|
|
|
|
tigloyl-CoA + pseudopelletierin-3-ol <=> CoA + 3-O-tigloyl-pseudopelletierin-3-ol
|
2.3.1.186
pseudotropine acyltransferase
|
–
|
|
|
BRENDA:
BS393677
|
|
|
|
tigloyl-CoA + 1-methylpiperidin-4-ol <=> CoA + O-tigloyl-4-hydroxy-1-methylpiperidine
|
2.3.1.186
pseudotropine acyltransferase
|
–
|
|
|
BRENDA:
BS393669
|
|
|
|
tigloyl-CoA + NAD+ <=> 3-oxo-2-methylacyl-CoA + NADH
|
1.1.1.35
3-hydroxyacyl-CoA dehydrogenase
|
–
|
|
|
BRENDA:
BS389884
|
|
|
|
tigloyl-CoA + NADPH <=> 2-methylbutanoyl-CoA + NADP+
|
1.3.1.8
acyl-CoA dehydrogenase (NADP+)
|
–
|
|
|
BRENDA:
BS258636
|
|
|
|
tigloyl-CoA + malonyl-[acyl-carrier_protein] <=> (4E)-4-methylhex-4-enoyl-[acyl-carrier_protein] + CoA + CO2
|
2.3.1.180
beta-ketoacyl-[acyl-carrier-protein] synthase III
|
–
|
|
|
BRENDA:
BS381011
|
|
|
|
tigloyl-CoA + glycine <=> CoA + N-tiglylglycine
|
2.3.1.71
glycine N-benzoyltransferase
|
–
|
|
|
BRENDA:
BS321264
|
|
|
|
2-methylbutanoyl-CoA + electron_acceptor <=> tigloyl-CoA + reduced_acceptor
|
1.3.8.1
short-chain acyl-CoA dehydrogenase
|
–
|
|
|
BRENDA:
BS395572
|
|
|
|
methyl-glutaryl-CoA + acceptor <=> tigloyl-CoA + reduced_acceptor
|
1.3.8.6
glutaryl-CoA dehydrogenase (ETF)
|
–
|
|
|
BRENDA:
BS258897
|
|
|
|
(R)-2-methylbutanoyl-CoA + acceptor <=> tigloyl-CoA + reduced_acceptor
|
1.3.99.12
2-methylacyl-CoA dehydrogenase
|
–
|
|
|
BRENDA:
BS370744
|
|
|
|
2-methylbutanoyl-CoA + FAD <=> FADH2 + tigloyl-CoA
|
1.3.8.4
isovaleryl-CoA dehydrogenase
1.3.8.7
medium-chain acyl-CoA dehydrogenase
1.3.99.12
2-methylacyl-CoA dehydrogenase
|
–
–
–
|
|
|
SABIO-RK:
3002
|
|
|
|
tigloyl-CoA + H2O <=> CoA + tiglic_acid
|
3.1.2.20
acyl-CoA hydrolase
|
–
|
|
|
SABIO-RK:
12798
|
|